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The Popsicle was accidentally invented by Frank Eperson when he forgot his fruit soda outside with a stir stick in it during winter. He called it the Epsicle, which was later renamed to Popsicle.
The Saxophone was invented by Adolphe Sax in the 1840s. He didn't gain much monetary compensation for his invention, and had to fight numerous attempts to copy his patent and even an attempt on his life.